Does it charge the phone when it is in the stand?

Since it doesn't have a separate power supply, the current available for peripheral devices will be limited to what it can draw from the USB 3.0 port on computer it's plugged into. So I wouldn't want to use it to charge a phone.

Can I use my keyboard and mice connecting with my desktop?

I have not had an issue with using my peripherals through the hub. The provided usb connectors can be a little temperamental when plugging into a cable extender.

Questions & Answers: USB HUB, ORICO 4 Port USB 3.0 Portable Data HUB with Phone holder, 3.3ft USB Cable Included, Support Phone Stand Function for Laptop, Notebook, PC, Surface Pro, Flash Drives, and Mobile HDD

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Item#: 9SIA1DS5262611
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USB HUB, ORICO 4 Port USB 3.0 Portable Data HUB with Phone holder, 3.3ft USB Cable Included, Support Phone Stand Function for Laptop, Notebook, PC, Surface Pro, Flash Drives, and Mobile HDD

4 x USB 3.0 Ports
Super Speed USB 3.0
5Gbps Transmission Rate
with Phone Tablet Holder
Portable and Compact
Convenience for your watching time
Support Mac OS, Windows, Vista, XP

$14^.99 –