Can mSATA drives be used with this motherboard?

There are no direct msata connections on the motherboard.

Is this motherboard compatible with SLI?

If you are looking to utilize the SLI or Crossfire format I would not recomend this MB for that. Find one that has a dual PCI Express 3.0 slots to do that for best performance.

Does this support Corsair Vengeance Pro 2400mhz ram?

The board supports up to 2800Mhz but you will have to set it in BIOS(overclocked). It supported any DDR3 I put in it and I did run my G.Skill at 2400. However using the OC features gives you no guarantee so you can set it at 2400 and see how it does. At worst I imagine it will run at 2200 or so but quality ram usually will clock just fine to its default.

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Hi-Fi Z87W Memory Compatibility

Hi-Fi Z87W CPU Compatibility

Main image of BIOSTAR Hi-Fi Z87W LGA 1150 Intel Z87 HDMI USB 3.0 ATX Intel Motherboard

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BIOSTAR Hi-Fi Z87W LGA 1150 Intel Z87 HDMI USB 3.0 ATX Intel Motherboard

Used - Very Good

Intel Z87
4th-Gen Intel Core i7 / i5/ i3 (LGA1150)
DDR3 2800(OC)/ 2600(OC)

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Specs

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Learn more about the Biostar Hi-Fi Z87W

Model
Brand	BIOSTAR
Model	Hi-Fi Z87W

Supported CPU
CPU Socket Type	LGA 1150
CPU Type	4th-generation Core i5, i7 (LGA1150)

Chipsets
Chipset	Intel Z87

Memory
Number of Memory Slots	4x240pin
Memory Standard	DDR3 2800(OC)/ 2600(OC)/ 2400(OC)/ 2200(OC)/ 2133(OC)/ 1866(OC)/ 1800(OC)/ 1600/ 1333/ 1066
Maximum Memory Supported	32GB
Channel Supported	Dual Channel

Expansion Slots
PCI Express 3.0 x16	1 x PCI Express 3.0 x16
PCI Express 2.0 x16	1(x4)
PCI Express x1	2 x PCI Express x1
PCI Slots	2 x PCI Slots

Storage Devices
Serial ATA (SATA)	6 x SATA 6Gb/s

Onboard Audio
Audio Chipset	Realtek ALC892
Audio Channels	8 Channels

Onboard LAN
Max LAN Speed	1Gbps

Rear Panel Ports
Back I/O Ports	1 x HDMI / 2 x USB 3.0 / 4 x USB 2.0/1.1
Video Ports	D-Sub + DVI
HDMI	1 x HDMI
USB 3.0	2 x USB 3.0
USB 1.1/2.0	4 x USB 2.0

Internal I/O Connectors
Onboard USB	2 x USB 3.0 + 4 x USB 2.0

Physical Spec
Form Factor	ATX
Dimensions (W x L)	12" x 8.6"

Features
Features	Heat-Sink: SB + Mosfet Hi-Fi Technology : Hi-Fi 10Phase VRD All Solid Cap

Additional Information
First Listed on Newegg	September 14, 2023

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Item#: 9SIA639K4W0656